diff --git a/doc/api.rst b/doc/api.rst
index 1bd4eee9b12..fbd0a75bb41 100644
--- a/doc/api.rst
+++ b/doc/api.rst
@@ -292,6 +292,7 @@ DataArray contents
    DataArray.swap_dims
    DataArray.expand_dims
    DataArray.drop_vars
+   DataArray.drop_duplicates
    DataArray.reset_coords
    DataArray.copy
 
diff --git a/doc/whats-new.rst b/doc/whats-new.rst
index 7994cad72e5..c07fecfb092 100644
--- a/doc/whats-new.rst
+++ b/doc/whats-new.rst
@@ -21,6 +21,10 @@ v0.18.1 (unreleased)
 
 New Features
 ~~~~~~~~~~~~
+
+- Implement :py:meth:`DataArray.drop_duplicates`
+  to remove duplicate dimension values (:pull:`5239`).
+  By `Andrew Huang <https://github.com/ahuang11>`_.
 - allow passing ``combine_attrs`` strategy names to the ``keep_attrs`` parameter of
   :py:func:`apply_ufunc` (:pull:`5041`)
   By `Justus Magin <https://github.com/keewis>`_.
diff --git a/xarray/core/dataarray.py b/xarray/core/dataarray.py
index 831d0d24ccb..dcda20dc451 100644
--- a/xarray/core/dataarray.py
+++ b/xarray/core/dataarray.py
@@ -4573,6 +4573,33 @@ def curvefit(
             kwargs=kwargs,
         )
 
+    def drop_duplicates(
+        self,
+        dim: Hashable,
+        keep: Union[
+            str,
+            bool,
+        ] = "first",
+    ):
+        """Returns a new DataArray with duplicate dimension values removed.
+        Parameters
+        ----------
+        dim : dimension label, optional
+        keep : {"first", "last", False}, default: "first"
+            Determines which duplicates (if any) to keep.
+            - ``"first"`` : Drop duplicates except for the first occurrence.
+            - ``"last"`` : Drop duplicates except for the last occurrence.
+            - False : Drop all duplicates.
+
+        Returns
+        -------
+        DataArray
+        """
+        if dim not in self.dims:
+            raise ValueError(f"'{dim}' not found in dimensions")
+        indexes = {dim: ~self.get_index(dim).duplicated(keep=keep)}
+        return self.isel(indexes)
+
     # this needs to be at the end, or mypy will confuse with `str`
     # https://mypy.readthedocs.io/en/latest/common_issues.html#dealing-with-conflicting-names
     str = utils.UncachedAccessor(StringAccessor)
diff --git a/xarray/tests/test_dataarray.py b/xarray/tests/test_dataarray.py
index e6c479896e9..8012fad18d0 100644
--- a/xarray/tests/test_dataarray.py
+++ b/xarray/tests/test_dataarray.py
@@ -7434,3 +7434,24 @@ def test_clip(da):
     # Unclear whether we want this work, OK to adjust the test when we have decided.
     with pytest.raises(ValueError, match="arguments without labels along dimension"):
         result = da.clip(min=da.mean("x"), max=da.mean("a").isel(x=[0, 1]))
+
+
+@pytest.mark.parametrize("keep", ["first", "last", False])
+def test_drop_duplicates(keep):
+    ds = xr.DataArray(
+        [0, 5, 6, 7], dims="time", coords={"time": [0, 0, 1, 2]}, name="test"
+    )
+
+    if keep == "first":
+        data = [0, 6, 7]
+        time = [0, 1, 2]
+    elif keep == "last":
+        data = [5, 6, 7]
+        time = [0, 1, 2]
+    else:
+        data = [6, 7]
+        time = [1, 2]
+
+    expected = xr.DataArray(data, dims="time", coords={"time": time}, name="test")
+    result = ds.drop_duplicates("time", keep=keep)
+    assert_equal(expected, result)